{"ModuleCode":"CM3212","ModuleTitle":"Transition Metal Chemistry","Department":"Chemistry","ModuleDescription":"This module covers the chemistry of d-block and f-block metals. An introduction to observed trend in physical and chemical properties of d-block transition metal complexes will be given. A comprehensive discussion on their electronic structures and spectra follows. Magnetic property, ligand substitution and redox reaction of these metal complexes will be illustrated. The f-block metals will be introduced leading to a discussion of the optical spectra of their complexes. Introduction to inorganic supramolecular chemistry, crystal engineering and solid state chemistry will be covered.","ModuleCredit":"4","Workload":"3-1-0-3-3","Prerequisite":"CM2111","ExamDate":"2015-11-30T17:00+0800","ExamDuration":"P2H","ExamVenue":"LT26","Types":["Module"],"Lecturers":["Chan Sau Han"],"IVLE":[{"Announcements":null,"Forums":[],"Workbins":[],"Webcasts":[],"Gradebooks":[],"Polls":[],"Multimedia":[],"LessonPlan":[],"ID":"2541a48c-c593-480f-a7e1-cf555ba862cb","CourseLevel":"1","CourseCode":"CM3212","CourseName":"TRANSITION METAL CHEMISTRY","CourseDepartment":"","CourseSemester":"Semester 1","CourseAcadYear":"2015/2016","CourseOpenDate":"/Date(1434988800000+0800)/","CourseOpenDate_js":"2015-06-23T00:00:00","CourseCloseDate":"/Date(1449331140000+0800)/","CourseCloseDate_js":"2015-12-05T23:59:00","CourseMC":"0","isActive":"Y","Permission":"S","Creator":{"UserID":null,"Name":"Chan Sau Han","Email":null,"Title":null,"UserGuid":"06cc4638-981f-47b4-9f14-6de1fe018aa2","AccountType":null},"hasGradebookItems":false,"hasTimetableItems":true,"hasGroupsItems":false,"hasClassGroupsForSignUp":false,"hasGuestRosterItems":false,"hasClassRosterItems":false,"hasWeblinkItems":true,"hasLecturerItems":true,"hasDescriptionItems":true,"hasReadingItems":true,"hasAnnouncementItems":false,"hasProjectGroupItems":false,"hasProjectGroupsForSignUp":false,"hasConsultationItems":false,"hasConsultationSlotsForSignUp":false,"hasLessonPlanItems":false,"Badge":0,"BadgeAnnouncement":0,"WebLinks":[{"ID":"78284436-8889-443c-b36a-71639bd58bca","URL":"http://chemwiki.ucdavis.edu/Physical_Chemistry/Kinetics/Reaction_Rates ","Description":"Reference for Section 3 - \"integrated rate laws\" ","Order":1,"Rating":2,"SiteType":""}],"Lecturers":[{"ID":"f844388f-7156-45d5-8cd3-c9979cdd78bf","User":{"UserID":null,"Name":"Chan Sau Han","Email":null,"Title":null,"UserGuid":"06cc4638-981f-47b4-9f14-6de1fe018aa2","AccountType":null},"Role":"Lecturer ","Order":1,"ConsultHrs":"By appointment (via email).
\r\n"}],"Descriptions":[{"ID":"1e5f053b-8835-4692-be49-41f07234cfff","Title":"Learning Outcomes","Description":"To understand the coordination chemistry of selected d-block metals and their features in M.S. and NMR spectra, and the use of Tanabe-Sugano diagram in transition metal chemistry. To understand the differences in several reaction mechanisms of d-block metal complexes. To learn some current topics in metallosupramolecular chemistry of d-block metals. To understand the general chemistry of f-block metals and their difference with d-block metals.
\r\n
\r\nAfter completing this module, students are able to identify and understand various kind of ligands, MO diagrams of metal-ligands multiple bonds and metal-metal multiple bonds, the coordination chemistry and spectroscopic properties of d-block metal complexes and explain them with Tanabe-Sugano diagram, M.S. and NMR spectra. Students are also able to explain the reaction mechanism of d-block metal complexes, and understand metallosupramolecular chemistry of d-block metals and general chemistry of f-block metals.","Order":1},{"ID":"2e5f053b-8835-4692-be49-41f07234cfff","Title":"Prerequisites","Description":"CM2111
\r\n
\r\n
\r\nREMARKS: 1H-NMR and 13C-NMR, which have been learnt in CM2101 & CM2121, will be used in CM3212 to investigate the coordinations and reaction mechanisms of the d-block metal complexes.","Order":2},{"ID":"3e5f053b-8835-4692-be49-41f07234cfff","Title":"Teaching Modes","Description":"Lectures & Tutorials","Order":3},{"ID":"4e5f053b-8835-4692-be49-41f07234cfff","Title":"Schedule","Description":"***The timetable comes from the University Class Timetable. Please check with Dean's Office for the latest updates.***
\r\n
\r\nLectures
\r\n
\r\n8:00 A.M. - 10:00 A.M. every Tuesday & Friday at LT26
\r\n
\r\n
\r\nSmall-group Tutorials* (the schedules are fixed by Department) - from week 3 to week 12 (Note: the format and details will be announced in the 1st lecture class)
\r\n
\r\nVenue: S9-05-13
\r\n
\r\nGroup 1 (TU1): Tuesday 12pm-1pm;
\r\nGroup 2 (TU2): Tuesday 1pm-2pm;
\r\nGroup 3 (WE1): Wednesday 2pm-3pm;
\r\nGroup 4 (WE2): Wednesday 3pm-4pm.
\r\n
\r\n* Enrollment of small-group tutorial is being held via CORS for NUS students. For exchange student(s), please contact me by email.
\r\n
\r\n
\r\nClosed-book Mid-term 1
\r\n
\r\nDate: 15th Sept. 2015 (Tue.; week 6)
\r\nTime: To be announced (during lecture hours)
\r\nVenue: To be announced
\r\nTest-1 Syllabus: To be announced (Refer IVLE-workbin)
\r\n
\r\n
\r\nClosed-book Mid-term 2
\r\n
\r\nDate: 3rd Nov. 2015 (Tue.; week 12)
\r\nTime: To be announced (during lecture hours)
\r\nVenue: To be announced
\r\nTest-2 syllabus: To be announced (Refer IVLE-workbin)
\r\n
\r\n
\r\nClosed-book Final Examination
\r\n
\r\nDate: To be announced
\r\nTime: To be announced
\r\nVenue: To be announced
\r\nExam syllabus: To be announced","Order":4},{"ID":"6e5f053b-8835-4692-be49-41f07234cfff","Title":"Syllabus","Description":"1. Coordination chemistry of selected first row, second row and third row of the metals of the d-block and their complexes, that covers various kinds of ligands and their classifcation, general introduction of 16- and 18-electron rules, introduction and molecular orbital description/diagrams for metal-ligand sigma-bonding, metal-ligand pi-bonding, metal-ligand multiple bonding, metal-metal multiple bonding, and etc.;
\r\n2. Spectroscopy in transition metal chemistry including the use of Tanabe-Sugano diagram, NMR spectra and mass spectra;
\r\n3. Reaction mechanisms of d-block metal complexes;
\r\n4. Metallosupramolecular chemistry of d-block metals;
\r\n5. General introduction of selected f-block metals and their complexes.
\r\n","Order":6},{"ID":"8e5f053b-8835-4692-be49-41f07234cfff","Title":"Assessment","Description":"Closed-book Mid-term Test 1 (written): 25%;
\r\nClosed-book Mid-term Test 2 (written): 25%;
\r\nClosed-book Final Examination (written): 50%.","Order":8},{"ID":"4fd4dff2-f718-4bdf-beea-5a4b421cfeb2","Title":"Workload","Description":"3-1-0-3-3
Workload Components : A-B-C-D-E \r\n
A: no. of lecture hours per week \r\n
B: no. of tutorial hours per week \r\n
C: no. of lab hours per week \r\n
D: no. of hours for projects, assignments, fieldwork etc per week \r\n
E: no. of hours for preparatory work by a student per week","Order":9}],"ReadingFormatted":[{"ID":"17cdb4c8-6f6c-4aa9-8d7d-bc8fa9e400f8","Title":"Inorganic chemistry","Author":"C. E. Housecroft, A. G. Sharpe","Edition":"4e","PubYear":"2012","ISBN":"9780273742753","Publisher":"Pearson","BookType":"References","AdditionalInfo":"","CompWebsite":"","Order":1},{"ID":"6a891cf5-043b-42f5-8f9c-bcb7a1765a41","Title":"Shriver & Atkins' inorganic chemistry","Author":"Atkins, P. W.","Edition":"","PubYear":"2010","ISBN":"9780199236176","Publisher":"Oxford University Press","BookType":"References","AdditionalInfo":"","CompWebsite":"","Order":2},{"ID":"30e54800-d5cb-4573-b69c-0f94db7ae41b","Title":"Coordination chemistry","Author":"Joan Ribas Gispert","Edition":"","PubYear":"2008","ISBN":"9783527318025","Publisher":"Wiley","BookType":"Supplementary","AdditionalInfo":"","CompWebsite":"","Order":3},{"ID":"ebe1334f-3d3d-4ec6-a851-923efa7c2f41","Title":"Supramolecular chemistry","Author":"Jonathan W. Steed, Jerry L. Atwood.","Edition":"","PubYear":"2009","ISBN":"9786612690556","Publisher":"Wiley","BookType":"Supplementary","AdditionalInfo":"Electronic book is available NUS-Library.","CompWebsite":"","Order":4},{"ID":"e2db1ca3-e6fb-41cc-a9ab-58bef7cf4725","Title":"Inorganic chemistry : principles of structure and reactivity","Author":"James E. Huheey, Ellen A. Keiter, Richard L. Keiter","Edition":"4e","PubYear":"1993","ISBN":"006042995X","Publisher":"HarperCollins College Publishers","BookType":"Supplementary","AdditionalInfo":"","CompWebsite":"","Order":5},{"ID":"e54841b8-cc4a-4478-8250-a448768e5558","Title":"Inorganic spectroscopic methods","Author":"Alan K. Brisdon","Edition":"","PubYear":"1998","ISBN":"0198559496","Publisher":"Oxford University Press","BookType":"References","AdditionalInfo":"","CompWebsite":"","Order":6},{"ID":"5186cc42-1005-49e4-935e-5e7c53462004","Title":"NMR spectroscopy in inorganic chemistry","Author":"Iggo, Jonathan A.","Edition":"","PubYear":"1999","ISBN":"0198558902","Publisher":"Oxford University Press","BookType":"References","AdditionalInfo":"","CompWebsite":"","Order":7},{"ID":"e0b2f6f5-65a9-495d-98e4-cd06e6300776","Title":"Introduction to spectroscopy","Author":"Donald L. Pavia","Edition":"","PubYear":"2009","ISBN":"9780495114789","Publisher":"Brooks/Cole, Cengage Learning","BookType":"Supplementary","AdditionalInfo":"","CompWebsite":"","Order":8}],"ReadingUnformatted":[]}],"Timetable":[{"ClassNo":"SL1","LessonType":"Lecture","WeekText":"Every Week","DayText":"Tuesday","StartTime":"0800","EndTime":"1000","Venue":"LT26"},{"ClassNo":"SL1","LessonType":"Lecture","WeekText":"Every Week","DayText":"Friday","StartTime":"0800","EndTime":"1000","Venue":"LT26"},{"ClassNo":"TU1","LessonType":"Tutorial","WeekText":"Every Week","DayText":"Tuesday","StartTime":"1200","EndTime":"1300","Venue":"S9-0513"},{"ClassNo":"TU2","LessonType":"Tutorial","WeekText":"Every Week","DayText":"Tuesday","StartTime":"1300","EndTime":"1400","Venue":"S9-0513"},{"ClassNo":"WE1","LessonType":"Tutorial","WeekText":"Every Week","DayText":"Wednesday","StartTime":"1400","EndTime":"1500","Venue":"S9-0513"},{"ClassNo":"WE2","LessonType":"Tutorial","WeekText":"Every Week","DayText":"Wednesday","StartTime":"1500","EndTime":"1600","Venue":"S9-0513"}],"CorsBiddingStats":[{"AcadYear":"2015/2016","Semester":"1","Round":"1A","Group":"Lecture Sl1","Quota":"110","Bidders":"54","LowestBid":"1","LowestSuccessfulBid":"1","HighestBid":"1000","Faculty":"Science","StudentAcctType":"Returning Students [P]"},{"AcadYear":"2015/2016","Semester":"1","Round":"1B","Group":"Lecture Sl1","Quota":"56","Bidders":"4","LowestBid":"1","LowestSuccessfulBid":"1","HighestBid":"56","Faculty":"Science","StudentAcctType":"Returning Students [P]"},{"AcadYear":"2015/2016","Semester":"1","Round":"1C","Group":"Lecture Sl1","Quota":"52","Bidders":"2","LowestBid":"13","LowestSuccessfulBid":"1","HighestBid":"3000","Faculty":"Science","StudentAcctType":"Returning Students [P]"},{"AcadYear":"2015/2016","Semester":"1","Round":"2A","Group":"Lecture Sl1","Quota":"50","Bidders":"2","LowestBid":"1","LowestSuccessfulBid":"1","HighestBid":"100","Faculty":"Science","StudentAcctType":"Returning 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