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\r\n\tCM1121 is a 1- semester course on basic organic chemistry that is intended for students majoring in chemistry. Hence it is designed for students who will be subsequently reading CM2121 and higher levels organic chemistry modules.
\r\n\t
\r\n\tStudents who are not intending to read organic chemistry modules beyond CM1121 are strongly advised to read CM1501.
\r\n\t
\r\n\tCM1121 deals primarily with the basic principles to understand the structure and reactivity of organic molecules. Emphasis is on substitution and elimination reactions and chemistry of various functional groups. You will be taught the concepts on how molecules can be constructed. Reactions mechanism, organic transformations and stereochemistry will also be discussed.
\r\n\tBY READING THIS MODULE, STUDENTS SHOULD BE ABLE TO:
\r\n\t
\r\n\t
\r\n\ti. Understand and be able to apply and evaluate simple organic reaction transformations, functional group
\r\n\t interconversion and C-C bond formation reactions.
\r\n\t
\r\n\r\n\tii. Understand the scope and limitations as well as the mechanisms of organic reactions.
\r\n\r\n\t
\r\n\t
\r\n\t
\r\n\r\n\tiv. Describe and explain currently held views of chemical bonding, and account for the chemical reactivity of
\r\n\t reactions.
\r\n\t
\r\n\tH2 pass in chemistry or its equivalent
\r\n","Order":2},{"ID":"3e5f053b-8835-4692-be49-41f07234cfff","Title":"Teaching Modes","Description":"This module will be conducted using the blended-learning model. All lectures have been prerecorded so that students can view them at home. After each chapter, students are required to work on the self-assessment tutorial questions. This will help the students to assess their understanding of the concepts covered in the chapter. In addition to the self-assessment tutorial questions, mass tutorials and small group tutorial questions are also provided. Students are required to work on these question before attending the tutorial sessions. Small group tutorial sessions consist of 2-hours of interactive, in-class discussions each week. .\r\n\t1. Interpret and construct organic structures using knowledge of hydrocarbon framework and functional groups of alkanes, alkenes and alkynes; alcohols, ethers, amines, nitro compounds, alkyl halides, aldehydes and ketones; carboxylic acids, esters, amides, nitrile, acyl chlorides and acetals. Understand and apply systematic nomenclature of organic structures
\r\n\r\n\t2. Interpret and construct structure of molecules using knowledge of atomic structure, atomic orbitals and hybridization
\r\n\r\n\t3. Evaluate chemical reactions in organic reactions and apply the use of curly arrows to represent reaction mechanisms in organic reactions.
\r\n\r\n\t4. Predict the reaction product(s) of nucleophilic addition to carbonyl group by hydrides, organometallic reagents, water and alcohol given the reaction conditions
\r\n\r\n\t5. Analyze the delocalization and conjugation of organic molecules using the structure of alkene, benzene, the allyl system, aromatic compounds as examples
\r\n\r\n\t6. Explain the terms acidity, basicity and pKa and evaluate the acidity and basicity of nitrogen and oxygen bases
\r\n\r\n\t7. Suggest synthetic route(s) to make C-C bonds (including reaction conditions) based on the the reaction of organometallic reagents with halo-compounds and C=O groups
\r\n\r\n\t8. Predict reaction product(s) of nucleophilic substitution at the carbonyl group of carboxylic derivatives given the reaction conditions
\r\n\t
\r\n\t9. Predict the reaction product(s) of the following types of reactions given the reaction conditions: (i) hemiacetal and acetal formation, (ii) reductive amination, and (iii) Wittig reaction
\r\n\t10. (a) Analyse the effects of temperature and nature of reactants and products on equilibrium constant. (b) Account for the preferential formation of thermodynamic or kinectic products, given the reaction conditions.
\r\n\r\n\t11. (a) Determine the stereochemical relationship given a number of molecules. (b) Determine whether a given compound is optically active and suggest ways to resolve the stereoisomer.
\r\n\r\n\t12. Predict which of the following mechanisms will occur, given the reaction conditions and reactants: (i) SN1, (ii) SN2, (iii) E1, (iv) E2, and (v) rearrangement
\r\n\t
\r\n\t13. Analyze the conformation of alkanes and cycloalkanes through the application of knolwedge in bond rotation, barriers to rotation and ring strain
\r\n\t14. Predict the product (include regiochemistry) of the following types of reactions, based on the understanding of elctrophilic addition to alkenes: (i) bromination, (ii) oxidation, and (iii) halolactonization.
\r\n\r\n\t15. Predict the reaction product(s) of electrophilic aromatic substitution of benzene, phenols and substituted benzenes given the reaction conditions.
\r\n\r\n\t16. (a) Predict the effects of conjugation and polarization on the nature of addition product. (b) Predict the reaction product(s) during conjugate addition of alcohols. (c) Predict the reaction product(s) during conjugate addition of copper (I) salt and organometallic reagents
\r\n","Order":6},{"ID":"8e5f053b-8835-4692-be49-41f07234cfff","Title":"Assessment","Description":"\r\n\tA quiz will be held on Monday, 2nd March 2015 (tentative)
\r\n\r\n\tFinal grade = 0.6 (examination score) + 0.3 (quiz score) + 0.1 (tutorial participation)
\r\n\r\n\t
\r\n","Order":8}],"ReadingFormatted":[{"ID":"16376e85-3184-4345-b3f4-8a2d406cc96a","Title":"Organic Chemistry","Author":"Jonathan Clayden et al","Edition":"2e","PubYear":"2012","ISBN":"9780199270","Publisher":"Oxford University Press","BookType":"Compulsory","AdditionalInfo":"","CompWebsite":"","Order":1}],"ReadingUnformatted":[]}],"Lecturers":["Lam Yulin"],"LecturePeriods":["Monday Morning"],"TutorialPeriods":["Friday Afternoon","Monday Afternoon","Thursday Morning","Thursday Afternoon","Tuesday Morning","Wednesday Afternoon"]}]}